
Recent advances and challenges associated with electrification (photovoltaics and wind), high-power-density electronic devices and machines, electrified transportation, energy conversion, and building air conditioning have re-invigorated interest in PCM thermal storage.1, 2, 3 Thermal storage using a PCM can buffer transient heat loads, balance generation and demand of renewable energy, store grid-scale energy, recover waste heat,4 and help achieve carbon neutrality.5 Compared with other energy storage methods such as electrochemical batteries, PCMs are attractive for their relatively low cost and ease of integration with readily available energy resources such as solar power.6,7 [pdf]
We also identify future research opportunities for PCM in thermal energy storage. Solid-liquid phase change materials (PCMs) have been studied for decades, with application to thermal management and energy storage due to the large latent heat with a relatively low temperature or volume change.
PCMs are energy storage materials that have considerably higher TES densities than sensible heat storage materials and are able to absorb or release large quantities of energy at a constant temperature by undergoing a phase change [ 12 ].
In this paper, a comprehensive review has been carried out on PCM microcapsules for thermal energy storage. Five aspects have been discussed in this review: classification of PCMs, encapsulation shell materials, microencapsulation techniques, PCM microcapsules’ characterizations, and thermal applications.
Thermal storage using PCMs has a wide range of applications, ranging from small-scale electronic devices (∼1 mm), to medium-scale building energy thermal storage (∼1 m), to large-scale concentrated solar power generation (∼100 m).
Figure 1 B is a schematic of a PCM storing heat from a heat source and transferring heat to a heat sink. The PCM consists of a composite Field’s metal having a large volumetric latent heat (≈315 MJ/m 3) and a copper (Cu) conductor having a high thermal conductivity (≈384 W/ (m ⋅ K)), to enable both high energy density and cooling power.
The quantification of system-level costs and benefits using thermo-economic analysis has the potential to promote PCM thermal storage techniques to a variety of broad applications. Moreover, the investigation of energy and environment policy in a country or region has the potential to avoid risks or to cater to local thermal storage development.
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